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    2. ASTM F467 Grade R50700

    ASTM F467/F467M Grade R50700 Alloy 4 Nuts Specification

    Commercially pure titanium nuts for industrial and marine applications.

    ASTM F467/F467M Grade R50700 Alloy 4 Nuts provide high tensile strength, excellent corrosion resistance, and outstanding durability in critical operating conditions.

    ASTM F467/F467M Chemical Composition

    ASTM F467/F467M Titanium and Titanium-Base Alloys A

    UNS Designation Number Alloy General Name Al C Fe Ti H N O Pd V Cr Mo Zr Sn Si Ru Residuals B
    each, max total, max
    ASTM F467/F467M Grade R50700 4 Titanium Gr 4 . . . 0.10 0.50 balance 0.0125 0.07 0.40 . . . . . . . . . . . . . . . . . . . . . . . . 0.1 0.4
    • (A) All reported values are maximums, unless a range is specified.
    • (B) A residual is an element present in a metal or an alloy in small quantities inherent to the manufacturing process but not added intentionally. Residual elements need not be reported unless a report is specifically required by the purchaser.
    • (C) Ruthenium and Palladium, or both, may be added to Grade 19 for enhanced corrosion resistance as negotiated between purchaser and vendor. Chemical analysis is not required unless specifically negotiated.

    ASTM F467/F467M Mechanical Requirements

    ASTM F467/F467M Mechanical Requirements (Inch)

    Alloy Mechanical Property Marking Hardness, min A Proof Stress, Hex Nut min, ksi Proof Stress, Heavy Hex Nut min, ksi B
    ASTM F467 Alloy Ti 4 F 467CT 200 HV 85 92
    • (A) For aluminum and titanium alloys hardness values are for information only.
    • (B) Proof stress values for heavy hex nuts are based on 1.08 times the value for corresponding regular hex nuts.
    • (C) Aluminum alloy 2024-T4 shall be supplied in naturally aged condition. This material is not recommended for nuts in sizes greater than 1/4 (0.250) in.

    ASTM F467M Mechanical Requirements (Metric)

    Alloy Mechanical Property Marking Hardness, min A Proof Stress, Mpa
    ASTM F467M Ti 4 F467MCT 200 HV 585
    • (A) For aluminum and titanium alloys hardness values are for information only.
    • (B) Aluminum alloy 2024-T4 shall be supplied in naturally aged condition. This material is not recommended for nuts in nominal thread diameter larger than M6.

    ASTM F467/F467M Tensile Stress Areas and Threads per Inch

    Nominal Size, in. Coarse Threads-UNC Fine Threads-UNF 8 Thread Series-8UN
    Threads/in. Stress Area A, in 2 Threads/in. Stress Area A, in 2 Threads/in. Stress Area A, in 2
    1/ 4 20 0.0318 28 0.0364 . . . . . .
    5/ 16 18 0.0524 24 0.0580 . . . . . .
    3/ 8 16 0.0775 24 0.0878 . . . . . .
    7/ 16 14 0.1063 20 0.1187 . . . . . .
    1/ 2 13 0.1419 20 0.1599 . . . . . .
    9/ 16 12 0.1820 18 0.2030 . . . . . .
    5/ 8 11 0.2260 18 0.2560 . . . . . .
    3/ 4 10 0.3340 16 0.3730 . . . . . .
    7/ 8 9 0.4620 14 0.5090 . . . . . .
    1 8 0.6060 12 0.6630 . . . . . .
    1 1/ 8 7 0.7630 12 0.8560 8 0.790
    1 1/ 4 7 0.9690 12 1.0730 8 1.000
    1 3/ 8 6 1.1550 12 1.3150 8 1.233
    1 1/ 2 6 1.4050 12 1.5810 8 1.492
    • (A) Tensile stress areas are computed using the following formula:
    • A s = 0.7854 [ D - 0.9743/n ]
      • where:
      • As = tensile stress area, in. 2 ,
      • D = nominal size (basic major diameter), in., and
      • n = number of threads per inch.

    ASTM F467/F467M Tensile Stress Areas and Threads per Metric

    Nominal Nut Diameter and Thread Pitch Stress Area, Amm 2 Nominal Nut Diameter and Thread Pitch Stress Area, Amm 2
    M6 × 1 20.1 M16 × 2 157
    M8 × 1.25 36.6 M20 × 2.5 245
    M10 × 1.5 58.0 M24 × 3 353
    M12 × 1.75 84.3 M30 × 3.5 561
    M14 × 2 115 M36 × 4 817
    • (A) Tensile stress areas are computed using the following formula:
    • As = 0.7854 (D − 0.9382P) 2
      • where:
      • As = tensile stress area, mm. 2 ,
      • D = nominal size (basic major diameter), mm., and
      • n = number of threads per mm.

    ASTM F467 Condition (Heat Treatment)

    Except as provided in 4.2.3, nuts are furnished in the condition below (4.2.2). When required, stress relieving is specified by the purchaser for all copper alloys and nickel alloys 400 and 405 (4.2.3). Unless otherwise specified, nuts may be hot pressed, cold formed or machined at the manufacturer's option (4.2.1).

    Alloy Condition
    Copper (all alloys) As formed or stress relieved at manufacturer's option
    Nickel alloys 400 and 405 As formed or stress relieved at manufacturer's option
    Nickel alloy 500 Solution annealed and aged
    Aluminum alloy 2024-T4 Solution treated and naturally aged
    Aluminum alloy 6061-T6 Solution treated and artificially aged
    Aluminum alloy 6262-T9 Solution treated, artificially aged, and cold worked
    Titanium 625 Annealed

    Frequently Asked Questions

    What is ASTM F467 Ti 4 (UNS R50700)?

    UNS R50700 is Ti 4, listed in Table 1 of ASTM F467-13ε2 as titanium Gr 4. Key composition limits: oxygen 0.40 % max, iron 0.50 % max, nitrogen 0.07 % max, titanium balance. Titanium nuts are furnished as formed (4.2.2).

    What hardness and proof stress do F467 Ti 4 nuts need?

    Table 2 requires a minimum hardness of 200 HV and a minimum proof stress of 85 ksi for hex nuts and 92 ksi for heavy hex nuts. Heavy hex values are 1.08 times the hex nut value (note B). For aluminum and titanium alloys the hardness values are for information only (note A). Where both proof load and hardness are tested, proof load governs acceptance (6.2).

    What is the proof load of a 1/2-13 UNC F467 Ti 4 nut?

    Proof load is the Table 2 proof stress times the Table 4 tensile stress area (13.2.1, tested per ASTM F606). For 1/2-13 UNC the stress area is 0.1419 sq in, so a hex nut must carry 12,062 lbf (85 ksi) and a heavy hex nut 13,055 lbf (92 ksi) without failure.

    How are F467 Ti 4 nuts marked and supplied?

    Each nut carries the manufacturer's symbol and the Table 2 marking F 467CT, raised or depressed (17.1). Unless otherwise specified, dimensions are to ASME B18.2.2 (7.1), threads are Class 2B to ASME B1.1 (7.2) and nuts are furnished without any additive chemical or metallic finish (8.2). Mating bolts, cap screws and studs are covered by ASTM F468 (1.2).

    References & Standards

    • ASTM F467-13ε2 - Standard Specification for Nonferrous Nuts for General Use (inch-pound; F467M is the metric companion, Note 1)
    • ASTM F468 - Nonferrous Bolts, Hex Cap Screws, Socket Head Cap Screws, and Studs for General Use (mating bolts, 1.2)
    • ASME B18.2.2 - Square and Hex Nuts (nut dimensions unless otherwise specified, 7.1)
    • ASME B1.1 - Unified Inch Screw Threads (Class 2B nut threads, 7.2)
    • ASTM F606 - mechanical test methods for proof load (13.2.1); ASTM E18 and E92 - Rockwell and Vickers hardness (13.2.2)
    • ASTM B154 - mercurous nitrate test for copper alloys (Supplementary Requirement S1)
    • ASTM B574 - nickel alloy rod (raw material for nickel alloy nuts, 4.1.1)
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